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POLYETHYLENE

Polyethylene is used more than any other thermoplastic polymer. There is a wide variety of grades and formulations available that have an equally wide range of properties. In general, the outstanding characteristics of polyethylene are:

Toughness

  • Ease of processing

  • Chemicalresistance

  • Abrasion resistance

  • Electrical properties

  • Impact resistance

  • Low coefficient of friction

  • Near-zero moisture absorption

The three most commonly used grades of polyolefin are: Low Density, High Density and Polypropylene.

LOW DENSITY POLYETHYLENE (LDPE)
LDPE, was the first of the polyethylenes to be developed. It is a corrosion resistant, low density extruded material that provides low moisture permeability. LDPE has a fairly low working temperature, soft surface and low tensile strength. It is an excellent material where corrosion resistance is an important factor, but stiffness, high temperature and structural strength are not important considerations.

Features

  • Lightweight

  • Formable

  • Impact Resistant

  • Excellent Electrical Properties

  • Machinable

  • Weldable

Fabrication

  • LDPE can be fabricated using the following techniques.

  • Hot gas welded

  • Fusion and butt welded

  • Ultra-sonic sealed

  • Die cut

  • Machined with wood or metal working tools

  • Vacuum formed

  • Thermo-formed

Applications

  • Chemical resistant tank and containers

  • Food storage containers

  • Laboratory equipment

  • Disposable Thermo-formed products

  • Corrosion resistant work surfaces

  • Vacuum formed end caps and tops

  • Moisture barrier

 

HIGH DENSITY POLYETHYLENE (HPDE)
HPDE is more rigid and harder than lower density materials. It also has a higher tensile strength, four times that of low density polyethylene, and it is three times better in compressive strength. HDPE meets FDA requirements for direct food contact applications. It also is accepted by USDA, NSF and the Canadian Department of Agriculture.

Features
Abrasion Resistant
The extremely high molecular weight of HDPE combined with its very low coefficient of friction provides and excellent abrasion resistant product preventing gouging, scuffing and scraping.

Exceptional Impact Strength
HDPE is one of the highest impact resistant thermoplastics available and maintains excellent machinability and self- lubricating characteristics. Properties are maintained even at extremely low temperatures.

Chemical Resistant
HDPE has very good chemical resistance of corrosives as well as stress cracking resistance (with the exception of strong oxidizing acids at elevated temperatures). Certain hydrocarbons cause only a light surface swelling at moderate temperature.

Water Resistant
Moisture and water (including saltwater) have no affect on HDPE. It can be used in fresh and salt water immersion applications.

Fabrication

  • HDPE can be fabricated using the following techniques:

  • Hot gas welded

  • Fusion and butt welded

  • Ultra-sonic sealed

  • Die cut

  • Machined with wood or metal working tools

  • Vacuum formed

  • Thermo-formed

HIGH DENSITY POLYETHYLENE (HPDE)
APPLICATIONS

 

  • Food cutting boards

  • Corrosion resistant wall coverings

  • Pipe flanges

  • Lavatory partitions

  • Man-hole covers in Chemical Plants

  • Radiation shielding

  • Self supporting containers

  • Prosthetic devices


  • Typical properties of polyethylene

    ASTM test Property Low density Medium density High density Ultrahigh molecular weight

    PHYSICAL

    D792 Specific gravity 0.910-0.925 0.926-0.940 0.941-0.965 0.928-0.941
    D792 Specific volume (in.�/lb.) 30.4-29.9 29.9-29.4 29.4-28.7 29.4
    D570 Water absorption, 24 hours, 1/8 inch thick (%) <0.01 <0.01 <0.01 <0.01

    MECHANICAL

    D638 Tensile strength (psi) 600-2,300 1,200-3,500 3,100-5,500 4,000-6,000
    D638 Elongation (%) 90-800 50-600 20-1,000 200-500
    D638 Tensile modulus (10~5 psi) 0.14-0.38 0.25-0.55 0.6-1.8 0.20-1.10
    D790 Flexural modulus (10~5 psi) 0.08-0.60 0.60-1.15 1.0-2.0 1.0-1.7
    D256 Impact strength, izod (ft-lb/in. of notch) No break 0.5-16 0.5-20 No break
    D785 Hardness, Rockwell R 10 15 65 67

    THERMAL

    C177 Thermal conductivity (10~4 cal-cm/sec-cm~2-�C) 8.0 8.0-10.0 11.0-12.4 11.0
    D696 Coefficient of thermal expansion (10~5 in./in.-�F) 5.6-12.2 7.8-8.9 6.1-7.2 7.8
    D648 Deflection temperature (�F)
    At 264 psi
    At 66 psi

    90-105
    100-121

    105-120
    120-165

    110-130
    140-190

    118
    170

    ELECTRICAL

    D149 Dielectric strength (V/mil) short time, 1/8-in. thick 460-700 460-650 450-500 900 kV/cm
    D150 Dielectric constant At 1kHz 2.25-2.35 2.25-2.35 2.30-2.35 2.30-2.35
    D150 Dissipation factor At 1kHz 0.0002 0.0002 0.0003 0.0002
    D257 Volume resistivity (ohm-cm) At 73�F, 50% RH 10~15 10~15 10~15 10~18
    D495 Arc resistance(s) 135-160 200-235 - -

    OPTICAL

    D542 Refractive index 1.51 1.52 1.54 -
    D1003 Transmittance (%) 4-50 4-50 10-50 -

     

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